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"What scale is used to measure the color of waste water?"

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"History of the APHA/Pt-Co/Hazen Color Scale"

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"Carbon Blackness [My], Jetness [Mc], Undertone [dM] and Tint Strength [T]"

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"Do you know what Molten Color is?"

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"How do I measure “clear and colorless” Surfactants?"

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"Do you have a source for liquid Saybolt and ASTM D1500 Color Standards?"

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"ASTM Industrial Test Methods for visual and instrumental APHA Color Scale"

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What scale is used to measure the color of waste water?

Posted on Dec 19, 2025 by HunterLab

“True Color”, “Apparent Color”, “Adams-Nickerson”, “Biodegradable Colour” are all the same name for what we call ADMI Color (American Dye Manufacturer’s Institute).

This metric is used to quantify the residual color of waste water due to the presence of colored minerals and dyes, humic breakdown substances and iron.

The ADMI (American Dye Manufacturers’ Institute) Color Index was developed to monitor the color of wastewater effluent as an indicator of water quality. ADMI is a single metric based on the Adams Nickerson (ANLab) color difference between water and the visual Pt-Co liquid color standards that is independent of hue.

“It has been estimated that annually up to 12% of the synthetic dyes used in textile manufacturing operations can be found in dye wastewater effluent. After being processed in treatment plants, 20% of those dye losses will enter the environment. The same mechanism that allows these colorants to bind so well with textile fibers also causes hydrolysis reactions with other wastewater components, or reduction in anaerobic sediments to produce obnoxious by-products.

As a result the dispersed dyes tend to remain resident in the environment for some time. The half-life of these dyes depends on the pH, temperature and surrounding medium (natural water or anaerobic sediment). The dominant hue of these colored effluents tends to be blue[1].”

The Adams Nickerson Chromatic Value formula was an attempt to transform CIE tristimulus color space into a visually uniform color space through the use of a single metric color difference value. It is based on the premise that if two colors of different hues, A and B, are perceived to be visually different to the same degree from a colorless water reference point, then the vector distance (originally calculated as a ANLab delta E) from the colorless point to A or B will be the same in the Adams Nickerson color difference space.

In the case of the ADMI scale, the APHA/Pt-Co liquid color standards[2] serve as a set of physical reference standards against which the dye effluent is rated using a total color difference correlation. For example, if a blue dye effluent is visually perceived to differ from distilled water to the same magnitude as a light yellow APHA/Pt-Co 100 standard solution from the same colorless water standard, then the blue effluent is assigned an ADMI rating of 100.

HunterLab has replaced this subjective visual judgment as to which APHA/Pt-Co standard solution the bluish effluent sample matches with an objective, colorimetric method using a dE* total color difference correlation to the APHA/Pt-Co liquid color standards. This correlation to assigns equivalent ADMI values to samples of textile wastewater effluent.

Prior to measurement, the bluish effluent sample is filtered or centrifuged to remove suspended colloidal particles until judged to be visually clear. The samples are brought to room temperature. As the color varies with pH, the pH is adjusted to 7.6 using H2SO4 or NaOH as necessary.

Posted in Chemical

History of the APHA/Pt-Co/Hazen Color Scale

Posted on Dec 19, 2025 by HunterLab

Bottles of APHA/Pt-Co/Hazen 500 color standard.

“APHA” stands for American Public Health Association Color Scale, the organization responsible for the original definition and implementation of this visual color scale as a standard method for rating water quality.

What Name Should You Use?

It is also called “Pt-Co” for Platinum-Cobalt Color as this visual color scale is based on stable liquid color standards made from chloroplatinate solutions. The scale ranges from distilled water at 0 (“water-white”) to a stock solution of 500 (parts per million of platinum cobalt to water). Intermediate Pt-Co color standards are made by dilution of the Pt-Co stock solution as described in ASTM D1209.

Another name used for this same color scale is “Hazen”, named after Allen Hazen, the chemist who first defined the color scale for the American Public Health Association. When referenced as “Hazen Color”, the range is often above the typical 500 units associated with the APHA/Pt-Co, as in “1500 Hazen Color”.

“APHA”, “Pt-Co” and “Hazen” are three names for the same color scale.

The name preferred in ASTM D1209 and ISO 6271 is the “Platinum-Cobalt Color” or Pt-Co, but “APHA” is name in most common use in industry. When used, the term “Hazen Units” (HU) may be found in product specifications.

Posted in Chemical

Carbon Blackness [My], Jetness [Mc], Undertone [dM] and Tint Strength [T]

Posted on Dec 19, 2025 by HunterLab

“Carbon black, also called charcoal black lamp black, pigment black, soot or black carbon, is a fine particle carbon pigment obtained as soot from the incomplete combustion of many different types of organic materials, such as natural gas, or oil. Carbon black is usually a fine, soft, black powder. It is very stable and unaffected by light, acids and alkalis. It is commonly used in printing and lithograph inks and in Chinese ink sticks. In industry, carbon black is used as a filtration material and a filler /pigment in coatings, rubber, plastics, paints, carbon paper, and crayons.

Some synonyms for carbon black pigment —- Channel black; lampblack; Pigment Black 6 and 7; CI 77266; gas black; diamond black; smoke black; soot black; flame black; furnace black; acetylene black; thermal black; graphite; charcoal black; coal black; bone black; vine black; sumi (Jap.); hiilimusta (Fin.); nero di carbone (It.); noir de carbone (Fr.).” Source: Dandong MB Carbon Black Pigment Co., Ltd, China www.mbssth.com

For how black is black, there are 3 metrics used to quantify the color quality of black created in a coating, plastic and rubber substrates.

Blackness My is a measure of the degree of blackness, directly related to the reflectance. Typical reflectance values are typically below 5% and can be below 1% for the best blacks. The bottom-of-scale standardization of the instrument sets a measured reference for 0%.

Blackness My = 100*log (Yn/Y)

Jetness Mc is the color dependent black value developed by K. Lippok-Lohmer. As the Mc value increases, the jetness of the masstone increases. Sample preparation is typically based on an opaque drawdown of a black masstone based on black pigment and binder.

Posted in Chemical

Do you know what Molten Color is?

Posted on Dec 19, 2025 by HunterLab

FAQ:”A client is asking me to measure something they call “Molten Color’. Do you have any information on this? Do Hunterlab instrument have a function for this color?”

“Molten Color” is not a defined color scale but refers to melting chemical crystalline or powder material such as Maleic or Phthalic Anhydride, into a liquid at an elevated temperature in the 140 – 250 C range.

Industrial Standard References for Molten Color Applications

APHA/Pt-Co Color measurement is a color quality attribute of BPA Bisphenol A, Cresylic Acids, Maleic and Phthalic Anhydride; Cresylic Acids and aromatic hydrocarbons prepared by heating to a liquid form.

  • ASTM D1686 Test Method for Color of Solid Aromatic Hydrocarbons and Related Materials in the Molten State (Platinum-Cobalt Scale)
  • ASTM D3366 Standard Test Method for Color of Maleic Anhydride and Phthalic Anhydride in the Molten State and After Heating (Platinum-Cobalt Scale)
  • ASTM D3627 Standard Test Method for Color of Cresylic Acids (“C” Series Standards)
  • ASTM D4789 Standard Test Method for Solution Color of Bisphenol A (4,4´-Isopropylidenediphenol)

ASTM – American Society of Testing and Materials, West Conshohocken, PA USA www.astm.org

Posted in Chemical

How do I measure “clear and colorless” Surfactants?

Posted on Dec 19, 2025 by HunterLab

FAQ: “We are in touch with a pharmaceutical company which is looking for a spectrophotometer to measure the color and appearance of cationic surfactants. Can you provide any information on this topic?”

Surfactants reduce the surface tension of a liquid as in the use of a dish detergent; the interfacial tensions between two liquids such as in the case of an oil spill in water, or of laundry detergent removing soil from clothes in water.

Surfactants have two parts within a single molecular structure  – a hydrophilic (or water-loving) head and a hydrophobic (water-repellent or oil-loving) tail. The hydrophobic part is typically a long hydrocarbon chain of different types. The polar hydrophilic head group can be non-ionic (no-charge), anionic (positive charge), cationic (negative charge) and zwitterionic (two opposite charges).

In terms of color and appearance quality, transparent surfactants are often visually described in product specification sheets as “clear and colorless”, almost “water white”, without apparent visual haze. “Colorless” in measurement terms, means being a close as possible to distilled water with only trace yellowness. Being “clear” means being as close to distilled water as possible in not scattering light.

How to Measure Surfactants on HunterLab Sphere Instruments

  1. Any of HunterLab’s diffuse d/8° sphere instruments such as UltraScan VIS or UltraScan PRO are appropriate for this application. Additional required accessories are a  50 mm path length transmittance cell (13-8573-20 or 20 mm path length cell ( 04-4592-00) and a Transmittance Cell Holder (C02-1005-481).
  2. Configure the Color Data View in EasyMatch QC software to display:
    1. CIE L*, a*, b* D65/10° or C/2° as a full color descriptor. While these values are good to report, APHA and Haze% will be the two metrics best able to distinguish slight lot differences in very clear and colorless surfactants.
    2. APHA-50 mm [C/2°] or Yellowness Index YI E313 [C/2°] to quantify trace yellowness.Typical purchase specifications indicate a maximum APHA value of 5 to 30, with distilled water being 0.
    3. Haze% to measure trace scattering to indicate how “clear” the sample is. DI water will have 0% haze. A visual difference in haze can typically be seen around 4%.
    4. As an optional metric, Y Total Transmittance can be configured to quantify the total amount of light passing through the sample with DI water as a reference for 100% transmittance.
  3. Standardize any HunterLab sphere instrument in TTRAN (Total Transmittance) LAV (Large Area of View) mode using:
    1. The Light Blocker to set 0% transmittance.
    2. The 50-mm path length transmittance cell filled with DI water and the white calibrated tile at the reflectance port to set 100% transmittance.
  4. As a recommended PQ (Performance Qualification) step, leave the cell with DI water in place at the TTRAN port. Then measure DI water as a product standard. If the instrument is set up correctly, distilled water in the 50 mm cell should measure closely to CIE L* = 100.0, a* = 0.0, b* = 0.0; APHA = 0.0; YI E313 [C/2] = 0.0; Haze% = 0.0 and Y Total Transmittance = 100.0.
  5. As an optional Application Diagnostic step, a liquid APHA Color standard can be purchased with nominal values similar to the product specification (APHA 5, 10, 20 or 30), then measured for APHA 50-mm and Haze% on the first day to establish baseline values. The measured baseline APHA value should closely match the assigned APHA value for the standard. The baseline Haze% should be low, typically < 1%. Measurements of the APHA liquid color standard should match the baseline values closely over time to affirm that your instrument is consistent in measuring APHA Color and Haze%.
  6. Proceed to measure batch lots of surfactants and report APHA and Haze% to document process differences by lot and conformance to product color and appearance specifications.

Posted in Chemical

Do you have a source for liquid Saybolt and ASTM D1500 Color Standards?

Posted on Dec 19, 2025 by HunterLab

Spectrum Quality Standards

These liquid visual color standards can be used as an independent test to verify instrumental Saybolt and ASTM D1500 Color measurement performance over time for these two visual color scales used to evaluate oil, oil additive and petrochemical color quality.

Spectrum Quality Standards Inc.

Houston, TX 77084 USA

+281-578-7575

www.spectrumstandards.com

List of available liquid Saybolt and ASTM D1500 Color standards for performance verification.

Spectrum Quality Standards is a small company that primarily makes GC and Physical Properties standards for the petroleum industry. Spectrum Quality also sells liquid Saybolt and ASTM D1500 color standards as defined in Appendix X1 of ASTM D6045.

You can buy a set if you want to check the entire range in each scale, or if your product purchase specification must be less than a maximum Saybolt or ASTM D1500 value, you could purchase an individual liquid standard at that level to monitor and document measurement performance over time.

Posted in Chemical

ASTM Industrial Test Methods for visual and instrumental APHA Color Scale

Posted on Dec 19, 2025 by HunterLab

APHA/Pt-Co/Hazen visual and instrumental methods

FAQ: “Does HunterLab have any documentation to show that the UltraScan VIS is compliant with ASTM 1209. One of our customers is having a problem regarding the method. Their client is using the manual visual method for performing the ASTM 1209 color test method whereas they use the UltraScan VIS. Can you explain the difference?”There are many industrial methods that reference the APHA/Pt-Co/Hazen color scale but two of the best are:

  • ASTM D1209 Standard Test Method for Color of Clear Liquids (Platinum Cobalt Scale) defines the visual APHA/Pt-Co/Hazen color scale for yellowness of clear liquids.
  • ASTM D5386 Standard Test Method for Color of Liquids Using Tristimulus Colorimetry defines the instrumental APHA/Pt-Co/Hazen color scale for yellowness of clear liquids that directly correlates to the visual ASTM D1209 method.

ASTM – American Society of Testing and Materials, West Conshohocken, PA USA www.astm.org

Posted in Chemical
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Most Related Posts

  • What scale is used to measure the color of waste water?
  • History of the APHA/Pt-Co/Hazen Color Scale
  • Carbon Blackness [My], Jetness [Mc], Undertone [dM] and Tint Strength [T]
  • Do you know what Molten Color is?
  • How do I measure “clear and colorless” Surfactants?
  • Do you have a source for liquid Saybolt and ASTM D1500 Color Standards?
  • ASTM Industrial Test Methods for visual and instrumental APHA Color Scale
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