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"APHA/Pt-Co/Hazen vs Gardner color scales: What’s the difference?"

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"Do you know of an independent test lab that can measure APHA/Pt-Co/Hazen Color?"

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"ASTM Industrial Test Methods for visual and instrumental APHA Color Scale"

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"How is ASTM D1003 Transmission Haze measured at levels > 30%?"

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"History of the APHA/Pt-Co/Hazen Color Scale"

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"What Path Length Cell should I use for APHA/Pt-Co/Hazen Color Measurement?"

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"What scale is used to measure the color of waste water?"

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APHA/Pt-Co/Hazen vs Gardner color scales: What’s the difference?

Posted on Jan 10, 2023 by Ken Phillips

Resin samples typically measured in Gardner Color

The APHA/Pt-Co/Hazen and Gardner visual color scales were both originally based on liquid chloroplatinate color standards but have different history and intended use.

Posted in Chemical

Do you know of an independent test lab that can measure APHA/Pt-Co/Hazen Color?

Posted on Jan 09, 2023 by Ken Phillips

Nessler Rack with 0-30-100-200-300-400-500 APHA Pt-Co Hazen liquid color standards

Contact the following and ask for “APHA/Pt-Co/Hazen Color testing per ASTM D1209 and D5386″.

Dallas Laboratories, Inc.

Dallas, TX 75215 USA
+214-421-1400
www.associatedlabs.com

Two global test labs are:

Intertek – Deer Park Lab
Deer Park, TX 77536 USA
+281 971 5600
www.intertek.com/petroleum

SGS North America Inc.
Houston, TX 77058 USA
+281-291-8392
www.sgsgroup.us.com

Posted in Chemical

ASTM Industrial Test Methods for visual and instrumental APHA Color Scale

Posted on Jan 09, 2023 by Ken Phillips

APHA/Pt-Co/Hazen visual and instrumental methods.

FAQ: “Does HunterLab have any documentation to show that the UltraScan VIS is compliant with ASTM 1209. One of our customers is having a problem regarding the method. Their client is using the manual visual method for performing the ASTM 1209 color test method whereas they use the UltraScan VIS. Can you explain the difference?”There are many industrial methods that reference the APHA/Pt-Co/Hazen color scale but two of the best are:

  • ASTM D1209 Standard Test Method for Color of Clear Liquids (Platinum Cobalt Scale) defines the visual APHA/Pt-Co/Hazen color scale for yellowness of clear liquids.
  • ASTM D5386 Standard Test Method for Color of Liquids Using Tristimulus Colorimetry defines the instrumental APHA/Pt-Co/Hazen color scale for yellowness of clear liquids that directly correlates to the visual ASTM D1209 method.

ASTM – American Society of Testing and Materials, West Conshohocken, PA USA www.astm.org

Posted in Chemical

How is ASTM D1003 Transmission Haze measured at levels > 30%?

Posted on Jan 09, 2023 by Ken Phillips

Haze 30 standard (R) as part of a D1003- calibrated set (L) of 1%, 5%, 10%, 20%, 30% haze standards (HL# CMR-2760).

FAQ: “We have a scientist here who is looking at films containing small bubbles and attempting to do measure them by measuring Haze% on a HunterLab spectrophotometer. I suspect her problem in obtaining numbers that “make sense” from what you get from just eyeballing the samples (and trying to look through them at the outlines of a object behind the film to gage the amount of regular transmittance) is that her samples have Haze% > 30 %, which means that a spectrophotometer (or even a haze meter) isn’t the appropriate tool to use for the analysis.

How is transmission haze measured at levels > 30%?”

Posted in Chemical

History of the APHA/Pt-Co/Hazen Color Scale

Posted on Jan 09, 2023 by Ken Phillips

Bottles of APHA/Pt-Co/Hazen 500 color standard.

“APHA” stands for American Public Health Association Color Scale, the organization responsible for the original definition and implementation of this visual color scale as a standard method for rating water quality.

What Name Should You Use?

It is also called “Pt-Co” for Platinum-Cobalt Color as this visual color scale is based on stable liquid color standards made from chloroplatinate solutions. The scale ranges from distilled water at 0 (“water-white”) to a stock solution of 500 (parts per million of platinum cobalt to water). Intermediate Pt-Co color standards are made by dilution of the Pt-Co stock solution as described in ASTM D1209.

Another name used for this same color scale is “Hazen”, named after Allen Hazen, the chemist who first defined the color scale for the American Public Health Association. When referenced as “Hazen Color”, the range is often above the typical 500 units associated with the APHA/Pt-Co, as in “1500 Hazen Color”.

“APHA”, “Pt-Co” and “Hazen” are three names for the same color scale.

The name preferred in ASTM D1209 and ISO 6271 is the “Platinum-Cobalt Color” or Pt-Co, but “APHA” is name in most common use in industry. When used, the term “Hazen Units” (HU) may be found in product specifications.

Posted in Chemical

What Path Length Cell should I use for APHA/Pt-Co/Hazen Color Measurement?

Posted on Jan 09, 2023 by Ken Phillips

FAQ: ” We are currently using a 10 mm path length and read in the 0 – 50 region for APHA/Pt-Co/Hazen Color, usually in the area of 10. Would you recommend a 10 mm path length with our equipment for this application?”

“APHA Color” is also known by two other names – “Pt-Co Color” and “Hazen units (HU)”. All three names represent the same color scale. As the APHA/Pt-Co/Hazen Color is dependent on the path length or thickness of the sample, it is important to:

  • Use the same cell path length for all measurements.
  • Report the cell path length as part of the measurement method if inter-instrument agreement of APHA/PtCo/Hazen Color values is important at multiple sites.

HunterLab’s instrument correlation to the visual APHA/Pt-Co/Hazen Color scale per ASTM D5386 allows the user to select a 10-mm, 20-mm or 50-mm path length cell by configuring the Color Data View in EasyMatch QC software to display “APHA-10mm”, “APHA-20mm” or “APHA-50mm”.

While any of these three cell path lengths can be used to effectively measure APHA/Pt-Co/Hazen Color, the optimal choice for cell path length choice is based on the following criteria:

  • A 10-mm path length cell is typically used for highly saturated or chromatic liquids, typically with APHA/Pt-Co/Hazen Color values > 300.
  • The easy-to-fill 20-mm path length cell is used for moderately chromatic liquids, and is the default cell path length when a wide APHA/Pt-Co/Hazen Color range of liquid colors is being measured from 0 (distilled water) to 500.
  • The longer 50-mm path length cell is preferred for clear or near clear liquids where APHA/Pt-Co/Hazen Color values < 30, and especially when APHA < 10.

Posted in Chemical

What scale is used to measure the color of waste water?

Posted on Jan 09, 2023 by Ken Phillips

“True Color”, “Apparent Color”, “Adams-Nickerson”, “Biodegradable Colour” are all the same name for what we call ADMI Color (American Dye Manufacturer’s Institute).

This metric is used to quantify the residual color of waste water due to the presence of colored minerals and dyes, humic breakdown substances and iron.

The ADMI (American Dye Manufacturers’ Institute) Color Index was developed to monitor the color of wastewater effluent as an indicator of water quality. ADMI is a single metric based on the Adams Nickerson (ANLab) color difference between water and the visual Pt-Co liquid color standards that is independent of hue.

“It has been estimated that annually up to 12% of the synthetic dyes used in textile manufacturing operations can be found in dye wastewater effluent. After being processed in treatment plants, 20% of those dye losses will enter the environment. The same mechanism that allows these colorants to bind so well with textile fibers also causes hydrolysis reactions with other wastewater components, or reduction in anaerobic sediments to produce obnoxious by-products.

As a result the dispersed dyes tend to remain resident in the environment for some time. The half-life of these dyes depends on the pH, temperature and surrounding medium (natural water or anaerobic sediment). The dominant hue of these colored effluents tends to be blue[1].”

The Adams Nickerson Chromatic Value formula was an attempt to transform CIE tristimulus color space into a visually uniform color space through the use of a single metric color difference value. It is based on the premise that if two colors of different hues, A and B, are perceived to be visually different to the same degree from a colorless water reference point, then the vector distance (originally calculated as a ANLab delta E) from the colorless point to A or B will be the same in the Adams Nickerson color difference space.

In the case of the ADMI scale, the APHA/Pt-Co liquid color standards[2] serve as a set of physical reference standards against which the dye effluent is rated using a total color difference correlation. For example, if a blue dye effluent is visually perceived to differ from distilled water to the same magnitude as a light yellow APHA/Pt-Co 100 standard solution from the same colorless water standard, then the blue effluent is assigned an ADMI rating of 100.

HunterLab has replaced this subjective visual judgment as to which APHA/Pt-Co standard solution the bluish effluent sample matches with an objective, colorimetric method using a dE* total color difference correlation to the APHA/Pt-Co liquid color standards. This correlation to assigns equivalent ADMI values to samples of textile wastewater effluent.

Prior to measurement, the bluish effluent sample is filtered or centrifuged to remove suspended colloidal particles until judged to be visually clear. The samples are brought to room temperature. As the color varies with pH, the pH is adjusted to 7.6 using H2SO4 or NaOH as necessary.

Posted in Chemical
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Most Related Posts

  • APHA/Pt-Co/Hazen vs Gardner color scales: What’s the difference?
  • Do you know of an independent test lab that can measure APHA/Pt-Co/Hazen Color?
  • ASTM Industrial Test Methods for visual and instrumental APHA Color Scale
  • How is ASTM D1003 Transmission Haze measured at levels > 30%?
  • History of the APHA/Pt-Co/Hazen Color Scale
  • What Path Length Cell should I use for APHA/Pt-Co/Hazen Color Measurement?
  • What scale is used to measure the color of waste water?
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